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-frozengrabber.proWorm-like assemblies of gold nanocrystals: submicron length scale and high-density nanowire arrays.
Dense arrays of ultrafine gold nanowires (NWs) with submicron length scale were directly fabricated on glass substrates using a facile and effective chemical synthesis method in which silver ions capped gold nanoparticles (AuNPs) grow into ultrafine NWs in a relatively short period of time. The size of the ultrafine NWs (typically a few tens of nm) is one order of magnitude smaller than that of the NWs produced by other methods, and they can grow into long NWs (> or =1 microm). Theoretical analysis indicates that the enhanced reactivity of the small AuNPs due to the size effect is the origin of the much shorter reaction time required for the NW growth. Thus, such ultrasmall NWs are more advantageous for potential applications in nanostructured electronic devices, biosensors, and solar cells. We demonstrate that the ultrafine NW arrays grown on glass substrates can be efficiently transferred onto other substrates, especially onto silicon wafer surfaces, to provide high-density arrays of ultrafine NWs on the order of 10(4) NWs/cm(2) at 01e38acffe
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